【摘 要】
：
The new copper complex { [Cu(CH3COO)2(bbtz)](H2O)2 } n 1 (bbtz = 1,4-bis(1 ,2,4-triazol-1-ylmethyl)benzene) was synthesized and the structure was determined by
【机 构】
：
Key Laboratory of Organic Synthesis of Jiangsu Province
论文部分内容阅读
The new copper complex { [Cu(CH3COO)2(bbtz)](H2O)2 } n 1 (bbtz = 1,4-bis(1 ,2,4-triazol-1-ylmethyl)benzene) was synthesized and the structure was determined by single-crystal X-ray diffraction. Crystal data: C16H22CuN6O6, monoclinic, space group P21/n, a = 12.589(5), b =6.455(2), c = 12.677(5) A, β= 98.748(9)°, V= 1018.2(7) A3, Mr = 457.95, Z = 2, Dc= 1.494 g/cm3,F(000) = 474,μ = 1.118 mm-1, R = 0.0463 and wR = 0.0939 for 1971 observed reflections with I ＞2σ(I). The crystal structure of 1 is a one-dimensional chain via the bridging flexible ligand bbtz.
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