Microwave-assisted hydroxylation of benzene to phenol with H2O2 over FeSO4/SiO2

• 作 者: LIU Tong WEI Xianyong ZHAO Jia
• 机 构: SchoolofChemicalEngineeringandTechnology,KeyLaboratoryofCoalConversionandNewCarbonMaterials
• 出 处: 矿业科学技术：英文版
• 发表日期: 2010年1期
• 关键词: 过氧化氢 苯酚 微波辅助 催化剂用量 羟化 硫酸亚铁 液相催化氧化 最佳反应条件 hydroxyl radicals Fenton catalytic cond
• 基金项目: This research work is supported by the National Natural Science Foundation of China （No.50921002）.

Hydroxyl radicals HO are generated under Fenton-like (Fe2++H2O2→HO?+OH?+Fe3+) catalytic conditions upon microwave irradiation. Liquid-phase direct catalytic oxidation of benzene to phenol was obtained using FeSO4 supported on silica gel as a solid catalys