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  5. Stereoselective C（sp^3）-C（sp^2） Negishi coupling of （2-amido-1-phenylpropyl）zinc compounds through t

Stereoselective C（sp^3）-C（sp^2） Negishi coupling of （2-amido-1-phenylpropyl）zinc compounds through t

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：thouden
【摘 要】
：
A controllable diastereoselective C(sp2)-C(sp3) Negishi coupling reaction of secondary benzylic zinc reagents with aryl bromides has been demonstrated for the f
【作 者】
：
TANG Shi LI ShuHua ZHOU Dong Z 
【机 构】
：
CollegeofChemistryandChemicalEngineering,TechnicalInstituteofPhysicsandchemistry
【出 处】
：
中国科学：化学英文版
【发表日期】
：
2013年9期
【关键词】
：
立体选择性 空间位阻 酰氨基 锌化合物 苯基 SP 交叉偶联反应 耦合 stereoselective  Negishi coupling  benzylic 
【基金项目】
：
the National Natural Science Foundation of China （21172227）, Jishou University （2012）
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A controllable diastereoselective C(sp2)-C(sp3) Negishi coupling reaction of secondary benzylic zinc reagents with aryl bromides has been demonstrated for the first time, forming medicinally important 1-arylphenylethylamines. In the presence of Pd(OAc) 2
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