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通过实验测量了Pr3+在氟化物玻璃中的光学吸收,根据Judd-Ofelt理论计算了Pr3+离子的振子强度、辐射跃迁几率、分支比等光谱参数。并通过对能级的拟合,给出了Pr3+在玻璃介质中的Slater参数、自旋-轨道耦合和电子组态相互作用参数。
The optical absorption of Pr3 + in fluoride glass was measured experimentally and the spectral parameters such as oscillator strength, radiation transition probability and branching ratio of Pr3 + ions were calculated according to Judd-Ofelt theory. And by fitting the energy level, the parameters of Slater parameter, spin-orbit coupling and electronic configuration interaction of Pr3 + in glass are given.