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阐述了双核酞菁钴磺酸盐(PDS)脱硫催化剂的抗CN~-中毒性能。并根据红外、电子顺磁共振和原子吸收等光谱测定及量子化学理论计算(EHMO)的结果,在分子-电子水平上提出了PDS自解CN-中毒的双中心机理。
The anti CN ~ - poisoning performance of binuclear phthalocyanine cobalt sulfonate (PDS) desulfurization catalyst was described. And based on the results of infrared spectroscopy, electron paramagnetic resonance and atomic absorption spectroscopy and quantum chemical theory (EHMO), we proposed the double center mechanism of PDS autolysis CN-poisoning at the molecular-electronic level.