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The title compound, [Mn(2,4,6-TMBA)2(H2O)3]n·2nH2O (1), where 2,4,6-TMBA=2,4,6-trimethylbenzoic acid, was synthesized and its crystal structure was determined by X-ray diffraction analysis. The crystal is of monoclinic, space group C2/c with a=2.929 9(6) nm, b=1.036 4(2) nm, c=8.222 04(17) nm, V=2.494 7(9) nm3, Z=4, M=471.40, Dc=1.255 g·cm-3, μ=0.571 mm-1, F(000)=996, Rint=0.029 4, R=0.037 6 and wR=0.094 9. The Mn atoms are octahedrally coordinated by two O atoms of two ligands and four O atoms of water. The carboxyl group coordinates to Mn(Ⅱ)in the mode of monodentate, while the O atoms of water molecules coordinates in bridging mode. The complex shows a one-dimensional chain structure bridged by water molecules. CCDC: 297750.
The title compound, [Mn (2,4,6-TMBA) 2 (H2O) 3] n · 2nH2O (1), where 2,4,6-TMBA = 2,4,6-trimethylbenzoic acid, was synthesized and its The crystal is of monoclinic space group C2 / c with a = 2.929 9 (6) nm, b = 1.036 4 (2) nm, c = 8.222 04 V = 2.494 7 (9) nm3, Z = 4, M = 471.40, Dc = 1.255 g · cm-3, μ = 0.571 mm- 1, F (000) = 996, Rint = 0.029 4, R = 0.037 6 and wR = 0.094 9. The Mn atoms are octahedrally coordinated by two O atoms of two ligands and four O atoms of water. The carboxyl group coordinates to Mn (II) in the mode of monodentate, while the O atoms of water molecules coordinates in bridging mode. The complex shows one-dimensional chain structure bridged by water molecules. CCDC: 297750.