An Electrochemically Stable 2D Covalent Organic Framework for High-performance Organic Supercapacito

• 作 者: Rashid Iqbal Amir Badshah Ying-Jie Ma Lin-Jie Zhi
• 机 构: CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and T
• 出 处: 高分子科学（英文版）
• 发表日期: 2020年5期
• 关键词: 2D COFs Electrochemically stable Electrode materials High energy density Organic

An electrochemically stable two-dimensional covalent organic framework,PI-COF,has been synthesized by a scalable soivothermal method.PI-COF possesses a highly crystalline structure,well-defined pores,high specific surface area,and cluster macrostructure.Thanks to these features,PI-COF can work as electrode materials in organic supercapacitors,exhibiting a specific capacitance of 163 F/g at 0.5 A/g over a wide potential window of 0-2.5 V.Moreover,PI-COF shows excellent rate performance,which can deliver 96 F/g even at a high current density of 40 A/g.Because of the high capacitance and wide potential window,PI-COF has achieved a superior energy density of 35.7 W.h/kg at a power density of 250 W/kg.Most importantly,due to the remarkable electrochemical stability,the PI-COF based device shows outstanding cycling stability with 84.1％ capacitance maintained (137 F/g) after 3.0 x 104 charged/discharged cycles at 1 A/g.This work should shed light on designing new COF-based electrode materials for supercapacitors and other electrochemical devices.