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A reaction interface between the aluminum and K_2ZrF_6 during molten salt reaction process was frozen by quenching the mold in water, and the interface structure was analyzed to determine the formation process of Al_3Zr. Results show that a clear conical interface existed between the K_2ZrF_6 and aluminum. A zirconium accumulation layer with the thickness of about 2–3 lm was formed at the aluminum side of the interface. Many initially formed Al_3Zr particles(with the size of 0.4–16 lm) distributed in this layer, most of which located at the interface. The morphology of Al_3Zr particles is closely related with their size. For the size of 0.4–1 lm, the Al_3Zr appeared as globular and ellipsoid shapes. When it grew to the size of 1–2 and 2–16 lm, it exhibited the rule cube shape, and rule cuboids shape, respectively.
A reaction interface between the aluminum and K_2ZrF_6 during molten salt reaction process was frozen by quenching the mold in water, and the interface structure was analyzed to determine the formation process of Al_3Zr. Results show that a clear conical interface existed between the K_2ZrF_6 and aluminum. Mostly formed aluminum 3 of particles (with the size of 0.4-16 lm) distributed in this layer, most of which located at the interface . The morphology of Al_3Zr particles is closely related with their size. For the size of 0.4-1 lm, the Al_3Zr was as globular and ellipsoid shapes. When it grew to the size of 1-2 and 2-16 lm, it exhibited the rule cube shape, and rule cuboids shape, respectively.