Electrodeposition, Structure and Corrosion Resistance of Nanocrystalline NiW Alloy

来源 :Chinese Journal of Chemistry | 被引量 : 0次 | 上传用户:initial1985
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NiW alloy was electrodeposited from the electrolyte solution containing sodium tungstate, nickel sulfate and ammonium citrate. The electrodeposition, heat treatment, structure, surface morphology and corrosion resistance in w=0.03 NaCl solution, of NiW alloys were studied by means of DSC, XRD, SEM and electrochemical techniques. The results showed that the obtained NiW alloy electrodeposit with W weight content (wW=0.471) was presented in more typical nanocrystalline. After heat treatment at 400 ℃ for 1 h, the phase structure of the deposits was not obviously changed whereas the agglomerate for the reunion of tiny grains on deposit surface caused the granule in a more smooth morphology, the microhardness was slightly increased and the corrosion resistance was enhanced. NiW alloy was electrodeposited from the electrolyte solution containing sodium tungstate, nickel sulfate and ammonium citrate. The electrodeposition, heat treatment, structure, surface morphology and corrosion resistance in w = 0.03 NaCl solution, of NiW alloys were studied by means of DSC, XRD, SEM and electrochemical techniques. The results showed that the obtained NiW alloy electrodeposit with W weight content (wW = 0.471) was presented in more typical nanocrystalline. After heat treatment at 400 ° C for 1 h, the phase structure of the deposits was not app changed while the agglomerate for the reunion of tiny grains on deposit surface caused the granule in a more smooth morphology, the microhardness was slightly increased and the corrosion resistance was enhanced.
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