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As it is very difficult to release boron energy completely,kinetic mechanism of boron is not clear,which leads to the lack of theoretical guidance for studying how to accelerate boron combustion.A new semi-empirical boron combustion model is built on the King combustion model,which contains a chemical reaction path;two new methods of plasma-assisted boron combustion based on kinetic and thermal effects respectively are built on the ZDPLASKIN zero-dimensional plasma model.A plasma-supporting system is constructed based on the planar flame,discharge characteristics and the spectral characteristics of plasma and boron combustion are analyzed.The results show that discharge power does not change the sorts of excited-particles,but which can change the concentration of excited-particles.Under this experimental condition,plasma kinetic effect will become the strongest at the discharge power of 40 W;when the discharge power is less than 40 W,plasma mainly has kinetic effect,otherwise plasma has thermal effect.Numerical simulation result based on plasma kinetic effect is consistent with the experimental result at the discharge power of 40 W,and boron ignition delay time is shortened by 53.8％ at the discharge power of 40 W,which indicates that plasma accelerates boron combustion has reaction kinetic paths,while the ability to accelerate boron combustion based on thermal effect is limited.