反-4-(反-4'-正丙基环己基)环己醇的合成与表征

• 作 者: 杨永忠 刘鸿 高仁孝 刘骞峰 李启贵
• 机 构: 西安近代化学研究所,西安近代化学研究所,西安近代化学研究所,西安近代化学研究所,西安近代化学研究所 瑞联近代电子材料有限公司,陕西西安710065,瑞联近代电子材料有限公司,陕西西安710065,瑞联
• 出 处: 化学研究与应用
• 发表日期: 2005年02期
• 关键词: 正丙基 环己基 环己醇 加氢 异构化 表征 环己烷 苯酚 加氢反应 异构化反应

The mixture containing trans and cis former of 4-(trans-4’-n-propylcyclohexyl)cyclohexanol was prepared by hydrogenation of 4-(trans-4’-n-propylcyclohexyl)phenol with ruthenium/carbon catalysts.Isomerization reaction was performed at 200℃ without separating catalysts,the mass ratio of trans former to cis former was 71.1:28.9,the yield of trans-4-(trans-4’-n-propylcyclohexyl)cyclohexanol was 56.3%.The product was characterized by IR,MS,DSC and~(13)C NMR.The possible reaction mechanism was also dicussed.

The mixture containing trans and cis former 4- (trans-4’-n-propylcyclohexyl) cyclohexanol was prepared by hydrogenation of 4- (trans-4’-n-propylcyclohexyl) phenol with ruthenium / carbon catalysts.Isomerization reaction was performed at The product was characterized by IR, MS (eluting at 200 ° C without separating catalysts, the mass ratio of trans former to cis former was 71.1: 28.9, the yield of trans-4- (trans-4’-n-propylcyclohexyl) cyclohexanol was 56.3% , DSC and ~ (13) C NMR. The possible reaction mechanism was also dicussed.