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在以季铵盐为催化剂,盐酸介质中,用芳基重氮盐与二茂铁反应,我们合成了一种新型含二茂铁基间苯二甲酸配体,并研究了它和邻菲咯啉与金属锌配位,通过X-射线单晶衍射对其结构进行了表征。结果表明:该配合物属单斜晶系,C2/c空间群,a=27.41(5),b=12.61(1),c=32.42(5),α=90.00°,β=92.81°,γ=90.00°,V=11 201(3),Z=8,F(000)=682,Dc=2.484 g/cm3。二茂铁二羧酸两氧原子并未参与锌配位。
In quaternary ammonium salt as catalyst, hydrochloric acid medium, with aryl diazonium salt and ferrocene reaction, we have synthesized a new ferrocenyl isophthalic acid ligand, and its and phenanthroline The coordination of zinc with metal zinc showed that its structure was characterized by X-ray single crystal diffraction. The results show that the complex belongs to the monoclinic space group C2 = c, a = 27.41 (5), b = 12.61 (1), c = 32.42 (5), α = 90.00 °, β = 92.81 °, γ = 90.00 °, V = 11 201 (3), Z = 8, F (000) = 682, Dc = 2.484 g / cm3. Ferrocenedicarboxylic acid two oxygen atoms did not participate in zinc coordination.