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硫杂酞菁、含硫取代基的四氮杂卟啉及其金属配合物由于具有优异的光、电及催化性能而日益受到重视.据此,我们以自制的1-甲硫基-2-苯甲酰硫基马来二腈(MBM)为原料,合成了2,7,12,17-四(甲硫基)-3,8,13,18-四(苯甲酸硫基)四氮杂卟啉H_2T(mbm)TAP及其Mg(Ⅱ)、Cu(Ⅱ)、Ni(Ⅱ)配合物MT(mbm)TAP,经IR、UV-Vis和DTA等进行了表征.
Sulfa phthalocyanines, tetrathia porphyrins containing sulfur substituents and their metal complexes have drawn increasing attention because of their excellent optical, electrical and catalytic properties.Accordingly, we have synthesized 1-methylthio-2- (Methylthio) -3,8,13,18-tetrakis (thio-benzoate) tetrakisazepine was synthesized from benzoylthiol maleated dinitrile (MBM) Porphyrin H_2T (mbm) TAP, Mg (Ⅱ), Cu (Ⅱ) and Ni (Ⅱ) complexes MT (mbm) TAP were characterized by IR, UV-Vis and DTA.