论文部分内容阅读
有关苯胺、苯酚类修饰电极前人做了大量工作,而对萘胺类物质的研究则相对较少.本文研究了萘胺聚合膜与过渡金属离子络合特性及其在碱性溶液中的电催化行为,发现聚萘胺薄膜经过渡金属离子处理后对某些氨基酸及抗坏血酸等有机酸的电氧化有催化作用,抗坏血酸浓度1×10~(-6)~1×10~(-4)mol/L范围内与催化电流值呈良好的线性关系.
For aniline, phenolic modified electrode predecessors did a lot of work, while the research on naphthylamine is relatively small.This paper studied the complexation characteristics of naphthyl amine polymeric membrane and transition metal ion and its alkaline solution Catalytic behavior of the poly (N - naphthylamine) film was investigated. The results showed that poly (naphthylamine) film catalyzed the electrooxidation of certain amino acids and ascorbic acid after the transition metal ion treatment. Ascorbic acid concentration was 1 × 10 -6 ~ 1 × 10 -4 mol / L range and catalytic current showed a good linear relationship.