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Three new iron(Ⅲ) phosphonate cage-like complexes with [Fe 4 ], [Fe 9 ] and [Fe 14 ] cores have been synthesized by solvothermal reaction with various starting materials. Magnetic studies show overall antiferromagnetic interaction presented in these cages.
Three new iron (Ⅲ) phosphonate cage-like complexes with [Fe 4], [Fe 9] and [Fe 14] cores have been synthesized by solvothermal reaction with various starting materials. Magnetic studies show overall antiferromagnetic interaction presented in these cages.