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The electrochemi luminescence 【ecl】 of a new reagent 6-【2-hydroxy-4-diethylaminophenylazo】-2, 3-dihydro-1, 4-phthatazine-1, 4-dione 【HDEA】 in basic aqueous solution was studied. Trace amount of silver【I】 showed significant effect on the efficiency of ligh