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The title compound 1-((5-(4-(4-chlorophenoxy)-2-chlorophenyl)-2,2,3-trimethyl-oxazolidin-5-yl)methyl)-1H-1,2,4-triazole (C21H22Cl2N4O2) has been synthesized and characterized by elemental analysis,IR,1H NMR,MS and single-crystal X-ray diffraction. The crystal belongs to the triclinic system,space group P1 with a=6.891(2),b=9.074(2),c=18.258(4) ,α=99.292(4),β=95.105(4),γ=108.068(3)o,C21H22Cl2N4O2,Mr=433.33,V=1059.3(4)3,Z=2,Dc=1.359 g/cm3,F(000)=452,μ=0.331 mm-1,the final R=0.0448 and wR=0.0994 for 3727 unique reflections. The dihedral angle between the oxazolidine ring taking an envelope conformation with a local pseudo-mirror and the triazole ring is 27.7(9)o. Weak intermolecular C-H???N hydrogen bonds and π-π interactions exist between the triazole rings of neighboring molecules,forming a three-dimensional network,which stabilizes the crystal structure. The primary biological test shows the target compound has certain fungicidal activity.
The title compound 1 - ((5- (4- (4-chlorophenoxy) -2-chlorophenyl) -2,2,3-trimethyl- oxazolidin-5-yl) C21H22Cl2N4O2) has been synthesized and characterized by elemental analysis, IR, 1H NMR, MS and single-crystal X-ray diffraction. The crystal belongs to the triclinic system, space group P1 with a = 6.891 (2), b = 9.074 , c = 18.258 (4) , α = 99.292 (4), β = 95.105 (4), γ = 108.068 (3) o, C21H22Cl2N4O2, Mr = 433.33, V = 1059.3 , Df = 1.359 g / cm3, F (000) = 452, μ = 0.331 mm-1, the final R = 0.0448 and wR = 0.0994 for 3727 unique reflections. The dihedral angle between the oxazolidine ring taking an envelope conformation with a local pseudo-mirror and the triazole ring is 27.7 (9) o. Weak intermolecular CH ??? N hydrogen bonds and π-π interactions exist between the triazole rings of neighboring molecules, forming a three-dimensional network, which stabilizes the crystal structure. The primary biological test shows the target compound has certain fungicidal activity.