Hydrothermal Synthesis and Structural Characterization of a Novel 3-D Open Framework Zinc Phosphate

• 作 者: 彭成栋 李雅丝 庄婷婷 殷凡文 曾庆新
• 机 构: College of Chemistry and Chemical Engineering, Fuzhou University,
• 出 处: 结构化学
• 发表日期: 2014年03期
• 关键词: hydrothermal monoclinic tetrahedral Zinc template membered chains diffractometer

One novel organically templated zincophophate(C5N2H14)·[Zn3(OH2)(PO4)2(HPO4)] has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction together with elemental analysis, infrared spectroscopy, thermogravimetric analysis, and powder X-ray diffraction. The title compound crystallizes in the monoclinic space group P21/n, with a = 9.7904(11), b = 14.0287(14), c = 11.8651(13) , β = 104.690(3), V = 1576.4(3) 3, Z = 4, T = 296(2) K, Mr = 601.31 and Dc = 2.533 g/cm3. The compound consists of a macroanionic [Zn3(OH2)(PO4)2(HPO4)]2- framework and(C5N2H14)2+ cations, and its structure is built up from ZnO3(OH2), ZnO4, HPO4 and PO4 tetrahedral units that result in 4, 8 and 10-ring channels.

One novel organically templated zincophophate (C5N2H14) · [Zn3 (OH2) (PO4) 2 (HPO4)] has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction together with elemental analysis, infrared spectroscopy, thermogravimetric analysis, and The title compound crystallizes in the monoclinic space group P21 / n with a = 9.7904 (11), b = 14.0287 (14), c = 11.8651 (13) V = 1576.4 (3) 3, Z = 4, T = 296 (2) K, Mr = 601.31 and Dc = 2.533 g / cm3 The compound consists of a macroanionic [Zn3 (OH2) ] 2-framework and (C5N2H14) 2+ cations, and its structure is built up from ZnO3 (OH2), ZnO4, HPO4 and PO4 tetrahedral units that result in 4, 8 and 10-ring channels.