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首次将含氮膦配体有机无机磷酸锆钯络合物应用于羰基化反应,结果表明,该类催化剂能使苄氯常压羰基化反应顺利进行,苯乙酸收率25.5%~70.2%,且具有重复使用性能.并考察了温度、溶剂、减中和剂及相转移催化剂对苄氯羰基化反应的影响.
For the first time, the organometallic zirconium phosphate palladium complex containing nitrogenous phosphine ligand was applied to the carbonylation reaction. The results showed that the carbonylation reaction of benzylic chloride could be carried out smoothly. The yield of phenylacetic acid was 25.5% ~ 70. 2%, and has reusable performance. The influences of temperature, solvent, neutralizer and phase transfer catalyst on the carbonylation of benzyl chloride were also investigated.