【摘 要】
：
The solubility parameters of cellulose acrylate substituted degree 2.12 (CEA) have been calculated from the measured retention data by inverse gas chromatograph
【机 构】
：
Heilongjiang Key Laboratory of Molecule Design and Preparation of Flame Retardant Materials
【基金项目】
：
Plan of National Science and Technology Sustentation of China
论文部分内容阅读
The solubility parameters of cellulose acrylate substituted degree 2.12 (CEA) have been calculated from the measured retention data by inverse gas chromatography at various temperatures. The weight fraction activity coefficients of the solvents at infinite dilution (Ω∞1), the Flory-Huggins thermodynamic interaction parameters between CEA and solvents (X∞12), the excess molar heats of mixing (△Hs1), the partial molar heats of mixing at infinite dilution (△H∞1), the solubility parameters of solvent (δ1), and the solubility parameters of CEA (δ2), were calculated at various temperatures. The δ2 of the CEA was 17.32, 18.00, 18.13, 18.54, 19.39 at 55, 60, 65, 70 and 75℃, respectively.
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