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A zinc(II) complex [Zn(bdc)(py)·H 2O] n (bdc=1,4-benzenedicarboxylate, py=pyridine) has been prepared and characterized. Single crystal X-ray diffraction analysis reveals that the complex crystallizes in the monoclinic space group P2 1/n with a=0.84823(3), b=0.91440(3), c=1.65141(2) nm, β=91.243(2)°, V=1.28057(6) nm 3, Z=4. The coordination geometry at each Zn(II) center is a distorted tetrahedron. Two independent bdc ligands in a herringbone pattern link alternatively four-coordinated Zn(II) centers into a one-dimensional polymeric chain. Hydrogen bonds among coordinated water molecules and uncoordinated oxygen atoms of two independent bdc ligands from different polymeric chains extend one-dimensional polymeric chains into a three-dimensional structure.
A zinc (II) complex [Zn (bdc) (py) · H 2O] n (bdc = 1,4-benzenedicarboxylate, py = pyridine) has been prepared and characterized. Single crystal X-ray diffraction analysis reveals that the complex crystallizes in the monoclinic space group P2 1 / n with a = 0.84823 (3), b = 0.91440 (3), c = 1.65141 (2) nm, β = 91.243 = 4. The coordination geometry at each Zn (II) center is a distorted tetrahedron. Two independent bdc ligands in a herringbone pattern link alternatively four-coordinated Zn (II) centers into a one-dimensional polymeric chain. Hydrogen bonds among coordinated water molecules and uncoordinated oxygen atoms of two independent bdc ligands from different polymeric chains extend one-dimensional polymeric chains into a three-dimensional structure.