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在有机化合物中引入氟原子,可带来許多物理、化学性质的新的特点。这不仅为現代新的技术的应用提供了条件,而且給闡明有机反应机理提示了有力証据。在短短的廿年中,氟有机化学已經成为有机化学重要之一支,这絕非偶然。 綜观已有材料,不难看出,在这一新兴的領城里,研究得最深、最广的,要算是含氟烯之制备和性貭。本文将綜述含氟烯类之离子型反应(包括双键的亲电、亲核加成,取代反应等)。
The introduction of fluorine atoms in organic compounds can bring many new features of the physical and chemical properties. This not only provided the conditions for the application of modern new technology, but also provided strong evidence for clarifying the organic reaction mechanism. It is no coincidence that Fluororganic chemistry has become an important organic chemistry in just 20 years. Looking at the existing materials, it is not difficult to see that in this emerging leader, the most studied and the most extensive are the preparation of fluorine-containing olefins and their properties. This article reviews the ionic reactions (including electrophilic, nucleophilic addition, substitution reactions, etc.) of fluoroolefins.