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N-(para-chloro)-phenyl iminodiacetic acid hydrate ethanol solvate ClC6H4N(CH2COOH)2· H2O·C2H5OH, Mr = 307.73, monoclinic, P21/n, Cu-Ka (λ=1. 5410(?)), a = 16. 732(1), b = 5. 337(1), c=16. 300(1)(?) ,β=108. 52(1)°, V = 1380. 1(?)3, Z = 4, Dc=1.481g.cm-3, * = 27. 172cm-1, F(000) = 648, final R = 0. 072 for 1610 observed reflections. The crystal structure consists of discrete molecule of N-(para-chloro)-phenyl iminodiacetic acid, hydrate as well as ethanol solvate. A big ring consisting of atoms O(3), C(3), C(4), N(1), C(2), C(1), O(2) and H(2) is nearly planar with the maximum deviation of the atom N(1) of 0. 54 (?). Owing to the intramolecular hydrogen bond O(2)-H(2)…O(3) , the bond C(3) -O(3) in the COOH group is longer than the bond C(3)-O(4).
(Para-chloro) -phenyl iminodiacetic acid hydrate ethanol solvate ClC6H4N (CH2COOH) 2 · H2O · C2H5OH, Mr = 307.73, monoclinic, P21 / n, Cu-Ka B = 5. 337 (1), c = 16.300 (1) (?), Β = 108.52 (1) °, V = 1380.1 (?) 3, Z = The crystal structure consists of a discrete molecule of N- (para-D-glucopyranosyl) 4, Dc = 1.481g.cm-3, * = 27. 172cm- 1, F (000) = 648, final R = 0. 072 for 1610 observed reflections. chloro) -phenyl iminodiacetic acid, hydrate as well as ethanol solvate. A big ring consisting of atoms O (3), C (3), C (4), N O (2) and H (2) are nearly planar with the maximum deviation of the atom N (1) of 0. 54 (?). Owing to the intramolecular hydrogen bond O ), the bond C (3) -O (3) in the COOH group is longer than the bond C (3) -O (4).