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以5-[2-(4-溴丁氧基)苯基]-10,15,20-三(对甲氧基苯基)卟啉和对羟基偶氮苯为原料,经取代反应合成新化合物5-[2-(对苯偶氮苯氧基)丁氧基]苯基-10,15,20-三[(对甲氧基苯基)]卟啉(2),2经配位反应合成了金属铜,锌配合物(2a)和(2b),其结构经UV-Vis,1H NMR,IR和元素分析表征。
New compounds were synthesized by the reaction of 5- [2- (4-bromobutoxy) phenyl] -10,15,20-tris (p-methoxyphenyl) porphyrin and p-hydroxy azobenzene Synthesis of 5- [2- (p-phenylazophenoxy) butoxy] phenyl-10,15,20-tris [(p- methoxyphenyl)] porphyrin (2) The metallic copper and zinc complexes (2a) and (2b) were characterized by UV-Vis, 1H NMR, IR and elemental analysis.