【摘 要】
：
The interactions between L-tryptophan(L-Trp) and water-soluble p-sulfonatocalix[4]- arene (SCX4) were investigated by spectrofluorometry. The effect of pH was d
【出 处】
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Chinese Chemical Letters
论文部分内容阅读
The interactions between L-tryptophan(L-Trp) and water-soluble p-sulfonatocalix[4]- arene (SCX4) were investigated by spectrofluorometry. The effect of pH was discussed. The interaction process was estimated from the thermodynamic viewpoint. The SCX4 was found to be able to adjust its conformation to fit the size of L-Trp, and the benzene of L-Trp penetrated into the hydrophobic cavity of SCX4. Meanwhile, the binding mechanism was further elucidated by 1H NMR and molecular mechanics calculations.
The interaction between L-tryptophan (L-Trp) and water-soluble p-sulfonatocalix [4] -arene (SCX4) were investigated by spectrofluorometry. The effect of pH was discussed. The interaction process was estimated from the thermodynamic viewpoint. The SCX4 was found to be able to adjust its conformation to fit the size of L-Trp, and the benzene of L-Trp penetrated into the hydrophobic cavity of SCX4. Meanwhile, the binding mechanism was further elucidated by 1H NMR and molecular mechanics calculations.
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