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Raman spectra of C_(60) filled single-walled carbon nanotubes(C_(60)@SWNTs) with diameters of 1.3–1.5 nm have been studied under high pressure. A plateau in the pressure dependence of the G-band frequency at around 10 GPa was observed in both experiments with 514 nm and 830 nm excitation lasers, which is similar to the high pressure behaviors of pristine SWNTs. This structural transition has been assigned to the transformation into a peanut-like structure of the nanotubes. At pressure below 2 GPa, no obvious Raman signature related to the structural transition of nanotubes was observed, unlike what has been reported for C_(70) filled nanotubes. We discussed this point in terms of the arrangement differences of C_(60) and C_(70)molecules inside the nanotubes. At higher pressure up to 15 GPa, a graphite-like pressure evolution was observed in our C_(60)@SWNTs.
Raman spectra of C_ (60) filled single-walled carbon nanotubes (C_ (60) @ SWNTs) with diameters of 1.3-1.5 nm have been studied under high pressure. A plateau in the pressure dependence of the G-band frequency at around 10 GPa was observed in both experiments with both 514 nm and 830 nm excitation lasers, which are similar to the high pressure behaviors of pristine SWNTs. This structural transition has been assigned to the transformation into a peanut-like structure of the nanotubes. GPa, no obvious Raman signature related to the structural transition of nanotubes was observed, unlike what has been reported for C_ (70) filled nanotubes. We discussed this point in terms of the arrangement differences of C_ (60) and C_ (70) molecules At higher pressures up to 15 GPa, a graphite-like pressure evolution was observed in our C_ (60) @ SWNTs.