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A biomimetic type transformation of vobasine (6) to koumine (1) is described and a pro-bable biogenetic pathway is proposed for the principal Gelsemium alkaloids gelsemine and koumine.
A biomimetic type transformation of vobasine (6) to koumine (1) is described and a pro-bable biogenetic pathway is proposed for the principal Gelsemium alkaloids gelsemine and koumine.