Effects of Phosphoric Acid on Liquefaction of Wood in Phenol and Optimum Liquefaction Processing Par

• 作 者: Zhang Qiuhui Zhao Zhao Guangjie Jie Shujun
• 出 处: 中国林学（英文版）
• 发表日期: 2004年期
• 关键词: wood liquefaction phenol residue rate liquefaction processing parameters

To clarify the influencing factors of liquefaction of wood in phenol using phosphoric acid as a catalyst and get its liquefaction technology, a study on the liquefaction technology of Chinese fir (Cunninghamia lanceolata) and poplar (triploid Populus tomentosa Carr) under different conditions was conducted. The results indicate that the residue rate decreases with the increase of liquefaction temperature, liquefaction time, catalyst content or liquid ratio. It is also found that the optimum condition of liquefaction for poplar is estimated as: the reaction temperature of 180 °C, the reaction time of 2.5 h, liquid ratio (phenol/wood ratio) of 4.5 and catalyst content of 8%, and 4.2% residue rate could be obtained. Under the processing parameters of temperature 180 °C, the reaction time of 2.5 h, liquid ratio (phenol/wood ratio) of 4 and catalyst content of 10%, the residue rate of Chinese fir can reach 5.6%.