Phase structure and temperature dependent luminescence properties of Sr_2LiSiO_4F:Eu~(2+) and Sr_2Mg

来源 :Journal of Rare Earths | 被引量 : 0次 | 上传用户:gzlwh
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Green-emitting Sr2LiSiO4F:Eu2+ and blue-emitting Sr2MgSi2O7:Eu2+ phosphors were synthesized by the conventional high temperature solid-state route, respectively. Their structures and photoluminescence properties were comparatively investigated. It was found that the mixture phases of Sr2MgSi2O7 and SrF2 were obtained when a part of Sr2+ in Sr2LiSiO4F was replaced by some amount of Mg2+ in order to design the possible SrMgLiSiO4F:Eu2+ phosphor. Based on the photoluminescence analysis, Sr2LiSiO4F:Eu2+ phosphor exhibited a green broad emission band of main peak at 513 nm under the excitation of 365 nm, while the Sr2MgSi2O7:Eu2+ and SrMgLiSiO4F:Eu2+ phosphor showed blue emission centered at 467 nm. The temperature dependent photoluminescence properties and room temperature decay time for the three kinds of phosphors were also discussed in this paper. Green-emitting Sr2LiSiO4F: Eu2 + and blue-emitting Sr2MgSi2O7: Eu2 + phosphors were synthesized by the conventional high temperature solid-state route, respectively. Their structures and photoluminescence properties were comparatively investigated. It was found that the mixture of of Sr2MgSi2O7 and SrF2 obtained when a part of Sr2 + in Sr2LiSiO4F was replaced by some amount of Mg2 + in order to design the possible SrMgLiSiO4F: Eu2 + phosphor. Based on the photoluminescence analysis, Sr2LiSiO4F: Eu2 + phosphor exhibited a green broad emission band of main peak at 513 nm under the excitation of 365 nm, while the Sr2MgSi2O7: Eu2 + and SrMgLiSiO4F: Eu2 + phosphor showed blue emission centered at 467 nm. The temperature dependent photoluminescence properties and room temperature decay time for the three kinds of phosphors were also discussed in this paper.
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