论文部分内容阅读
二元和多元有机酸的氮丙啶衍生物,可用做含羧聚合物的链伸展剂或固化剂。二茂铁的多种衍生物是调节固体推进剂燃速的有效催化剂。如果二茂铁分子含有两个活泼的氮丙啶基,这种化合物将具有燃速催化和链伸展的双重作用。因此,研究二茂铁二甲酰氮丙啶化合物的合成,不仅可以制备一类新型二茂铁衍生物,而且对固体推进剂也具有重要的实际意义。我们研究了1,1’-二茂铁二甲酰氯在不同条件下与氮丙啶的缩合反应,合成了三种新的二茂铁氮丙啶衍生物,即1,1’-二茂铁二甲酰氮丙啶,1,1’-二茂铁二甲酰(2-甲基)氮丙啶
Aromatic and polybasic aziridine derivatives of organic acids can be used as chain extending or curing agents for carboxyl-containing polymers. Various derivatives of ferrocene are effective catalysts for regulating the burning rate of solid propellants. If the ferrocene molecule contains two lively aziridinyl groups, the compound will have the dual effect of burning rate and chain extension. Therefore, the study of ferrocarbazide synthesis, not only can prepare a new class of ferrocene derivatives, but also has important practical significance for solid propellants. We studied the condensation reaction of 1,1’-ferrocene dichloride with aziridine under different conditions and synthesized three new ferrocene aziridine derivatives, namely 1,1’-ferrocene Dicarboximide, 1,1’-ferrocene (2-methyl) aziridine