Synthesis and Crystal Structure of （R）-4-Hydroxymethyl-2-thioxo Thiazolidine and Its Asymmetric Cat

• 作 者: LI Jing SHANG Yan-mei XIAO Chu
• 机 构: CollegeofChemistry,SchoolofPublicHealth,KeyLaboratoryforSupramoleeularStructureandMaterialsofMinistr
• 出 处: 高等学校化学研究：英文版
• 发表日期: 2009年1期
• 关键词: 晶体结构 合成 (R)-4-羟甲基-2-硫代噻唑 不对称催化 Crystal structure Asymmetric （R）-4-Hydroxymethy

(R)-4-Hydroxymethyl-2-thioxo thiazolidine as a new chiral catalyst in the asymmetric addition of diethyl-zinc to benzaldehyde was synthesized from(R)-4-hydroxymethyl-2-thioxo thiazolidine carboxylic acid and its crystal structure was determined by X-ray d