The crystal structure and conformation of 15phenyl-bicyclo[10.3.0]pentadec-1(12)-en-13-one

来源 :Chinese Journal of Chemistry | 被引量 : 0次 | 上传用户:gaochuwuyu
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The title compound has been synthesized and its crystal structure determined by X-ray crystal-lographic method.The crystal is monoclinic,space group C2/c,with unit cell dimensions a=19.260(3),b=11.217(1),c=15.997(1)/n;β=92.08(2)°and Z=8.This is the first crystal structure determined in the series of bicyclo[10.3.0]pentadec-1(12)-en-13-one derivatives.The structure and the conformation of the cis-cyclododecene moiety in thiscompound is demonstrated to be closely similar to the lowest energy conformer[lene 2333]. The title compound has been synthesized and its crystal structure determined by X-ray crystal-lographic method. The crystal is monoclinic, space group C2 / c, with unit cell dimensions a = 19.260 (3), b = 11.217 = 15.997 (1) /n;β=92.08 (2) ° and Z = 8.This is the first crystal structure determined in the series of bicyclo [10.3.0] pentadec-1 (12) -en-13-one derivatives The structure and the conformation of the cis-cyclododecene moiety in this compound is demonstrated to be similar to the lowest energy conformer [lene 2333].
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