【摘 要】
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The FT-IR spectra of the[Cl_2FeS_2MoS_2FeCl_2]~(2-) dianion were measured in the range500 to 100 cm~(-1).A simplified general valence force field was used in a
【出 处】
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Acta Chimica Sinica(English Edition)
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The FT-IR spectra of the[Cl_2FeS_2MoS_2FeCl_2]~(2-) dianion were measured in the range500 to 100 cm~(-1).A simplified general valence force field was used in a normal coordinate analysis.The calculated frequencies agree well with the observed values,with a mean deviation of less than1.0%,thus confirming the assignments of the vibrational spectrum.Altogether 16 force constants,including stretching,bending,torsion and stretching-stretching interactions were obtained.Therationality and the reliability of the results were discussed.
The FT-IR spectra of the [Cl_2FeS_2MoS_2FeCl_2] ~ (2-) dianion were measured in the range 500 to 100 cm -1. A simplified general valence force field was used in a normal coordinate analysis. The calculated frequencies agree well with the observed values, with a mean deviation of less than 1.0%, thus confirming the assignments of the vibrational spectrum. Altogether 16 force constants, including stretching, bending, torsion and stretching-stretching interactions were obtained. The rationality and the reliability of the results were discussed.
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