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根据简正坐标分析的部分结果对标题配合物的实测红外和拉曼光谱进行了标识．计论了Ｃ＝Ｃ，Ｎ－Ｓ伸缩振动频率随配合物氧化态变化而红移或兰移的规律及意义．
The measured infrared and Raman spectra of the title complex were identified based on the partial results of simple coordinate analysis. The regularity and significance of the red shift or blue shift of the C = C, N-S stretching vibration frequency with the change of the complex oxide state are discussed.