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本文用电子顺磁共振法对某些酸性磷(膦)酸酯VO(Ⅱ)配合物在四氢呋中的氧化过程进行了动力学研究,研究了温度、浓度和配合物性质对反应速度及反应可逆性的影响,并计算得到动力学参数-氧化反应级数,反应速度常数和反应的表观活化能。
In this paper, the electron paramagnetic resonance method was used to study the kinetics of oxidation of certain acidic phosphine (phosphonate) VO (Ⅱ) complexes in tetrahydrofurane. The influences of temperature, concentration and complex on the reaction rate and Reaction reversibility, and calculated kinetic parameters - the oxidation reaction series, the reaction rate constant and the apparent activation energy of the reaction.