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采用恒电流阴极还原法、Ｘ射线衍射（ＸＲＤ）和Ｘ射线光电子能谱（ＸＰＳ）对铜在ＮａＯＨ浓溶液中的两种阳极钝化膜进行了研究。结果表明，铜表面一次钝化膜由Ｃｕ２Ｏ和Ｃｕ２Ｏ·Ｈ２Ｏ组成，二次钝化膜由Ｃｕ２Ｏ内层和ＣｕＯＣｕ（ＯＨ）２Ｈ２Ｏ（ａｄ）外层组成，且外层各组分的相对含量呈规律性深度分布。对Ｃｕ（Ⅱ）物相的形成历程进行了讨论
Two kinds of anodic passivation films of Cu in concentrated NaOH solution were investigated by galvanostatic reduction, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results show that the primary passivation film on the copper surface consists of Cu2O and Cu2O · H2O, the secondary passivation film consists of the inner Cu2O layer and the outer layer of CuOCu (OH) 2H2O (ad) Relative content showed a regular pattern of depth distribution. The formation of Cu (Ⅱ) phase is discussed