Removal of TOC and Color in Bleaching Effluents from Straw Pulp and Paper Mill by Fe~0-H_2O_2 Proces

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TOC and color in the bleaching effluent from straw pulp paper process could not reach draining standard after its treatment by a biochemical process. In this study, advanced treatment by integrated micro-electrolysis (Fe 0 ) method and Fenton-like process was investigated under various conditions, i.e. pH, Fe/C ratio, initial H_ 2 O_ 2 concentration and carrier gas. Results showed that Fe/C ratio(V/V= 1.5) , larger H_ 2 O_ 2 dosage around 50 mg/L, lower pH(pH=3) turned out to be particularly efficient. Temperature was a key parameter, remarkably increasing reaction rates. Carrier air not only improved reaction efficiency, but also saved H_ 2 O_ 2 dosage. Chlorinated organic compounds could be reductive dechlorinated by Fe 0 reaction and oxidated by ·OH produced from Fenton process. The combination of Fe 0 and H_2O_2 reactions had been proved to be highly effective for the advanced treatment of such a type of wastewaters, and important advantages concerning the application in the study. TOC and color in the bleaching effluent from straw pulp paper process could not reach draining standard after its treatment by a biochemical process. In this study, advanced treatment by integrated micro-electrolysis (Fe 0) method and Fenton-like process was investigated under various The results showed that Fe / C ratio (V / V = ​​1.5), larger H 2 O 2 dosage around 50 mg / L, lower pH ( pH = 3) turned out to be particularly efficient. Temperature was a key parameter, remarkably increasing reaction rates. and oxidated by · OH produced from Fenton process. The combination of Fe 0 and H 2 O 2 reactions had been proved to be highly effective for the advanced treatment of such a type of wastewaters, and important properties concerning the application in the study .
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