Syntheses and Structures of Two Heteronuclear Complexes with Glycine {[CuEr（Gly）5（H2O）2] （ClO4）5

• 作 者: 李宗圣 孙豪岭 寇会忠 韩士田 高松
• 机 构: CollegeofChemistryandMolecularEngineering,DepartmentofChemistry
• 出 处: 中国稀土学报：英文版
• 发表日期: 2002年5期
• 关键词: 稀土 杂环化合物 晶体结构 甘氨酸 磁性能 铜 配合物 rare earths heteronuclear complex crystal structure
• 基金项目: ProjectsupportedbytheStateKeyProjectofFundamentalResearch (G19980 6 13 0 5 ) ,,theNationalScienceFundforDistin guishedYoungScholars ( 2 0 12 5 10 4)andNSFC ( 2 0 0 2 3 0 0 5 ) ,,theResearchFundfortheD

Two one-dimensional heterometallic coordination polymers {[CuEr(Gly)5(H2O)2](ClO4)5·H2O}n (1) and {[Cu2Gd2(Gly)10(H2O)4](ClO4)10·4H2O}n(2)(Gly=glycine) were synthesized and structurally and characterized magnetically. Complex l crystallizes in a