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合成了３个系列芳香类含碳一氧键的化合物，用循环伏安法测定了相关的氧化还原电势，通过热力学循环首次估测了负离子基的碳—氧键的断裂能量（ΔＨ（ｃｌｅａｖ）［Ｃ－Ｏ］（·－））．结果表明：得到１个电子形成负离子基可以活化碳—氧键．这与具有相同结构的正离子基的情况是一致的，但其活化程度略小．相关分析表明：ΔＨ（ｃｌｅａｖ）［Ｃ－Ｏ］（·－）ｖｓ（ΔＥ（ｒｅｄ）［Ｃ－Ｏ］＋ΔｐＫａ［ＨＡ］）和ΔＨ（ｃｌｅｓｖ）［Ｃ－Ｏ］（·＋）ｖｓ．（ΔＢＤＥ－ΔＥ（ｏｘ）［Ｃ－Ｏ］）均呈线性．讨论了负离子基和正离子基及其母体化合物中键的特征，并与文献中有关的键能数据进行了比较。
Three series of aromatics compounds with carbon monoxide bond were synthesized. The redox potential was determined by cyclic voltammetry. The energy (ΔH (cleav) [C-O] (- -)). The results show that one electron can form anions to activate carbon-oxygen bond. This is consistent with the case of the positive ion group of the same structure, but with a lesser degree of activation. Correlation analysis showed that: ΔH (cleav) [C-O] (· -) vs (ΔE (red) [C-O] + ΔpKa [HA]) and ΔH (clesv) [C-O] (· +) vs. (ΔBDE-ΔE (ox) [C-O]) are linear. The characteristics of the bonds in anions and cations and their parent compounds are discussed and compared with those in the literature.