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本文提出了稀土—间硝基偶氮氯膦,稀土-间硝基偶氮氯膦-二苯胍的两个极谱络合吸附波体系,并用库仑分析,对照实验和循环伏安等方法研究了间硝基偶氮氯膦的电化学行为,解释了单扫极谱上各个波峰的电极过程。稀土与间硝基偶氮氯膦的络合部位在分子的氯膦一侧。络合物中氯膦一侧偶氮基酶还原形成了络合吸附峰。
In this paper, two polarographic adsorption wave systems of rare earth-m-nitro-chlorophosphonazo and rare earth-m-nitro-chlorophosphonazo-diphenylguanidine are proposed and studied by Coulomb analysis, control experiment and cyclic voltammetry The electrochemical behavior of nitro-chlorophosphonates explains the electrode processes at each peak in single-sweep polarography. Rare earth and m-nitro-chlorophosphonated complex on the molecular side of the phosphine. Complexes in the phosphine side of the azo-enzyme was reduced to form a complex adsorption peak.