Solventless ketalization of glycerol to solketal with acetone over the ionic liquid[P(C4H9)3C14H29][

• 作 者: Yu Ji Tengda Zhang Xia Gui Hai
• 机 构: CollegeofChemistryandChemicalEngineering
• 出 处: 中国化学工程学报:英文版
• 发表日期: 2020年1期
• 关键词: Ionic liquid KETALIZATION Solketal GLYCEROL Reaction kinetics Reactive DISTILLAT
• 基金项目: the National Key Research and development Program of China(2017YFB0307302),the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD).

The ketalization of glycerol with acetone was conducted over an ionic liquid[P(C4H9)3C14H29][TsO](TTPT)in a batch reactor.A scheme to obtain the purified product using TTPT as a homogeneous catalyst is proposed and a maximum solketal yield of 86%is achiev