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如何建立反应速率方程是复相催化反应动力学中的一个重要内容。以往在讲授这一节内容时,大都只介绍常规的平衡处理法和准稳态处理法,现有的一些教科书以及国内出版的专业书也都很少介绍“二步序列法”。该法是在前二种方法的基础上简化了确立方程的过程、且能给予所有常数以明确的物理意义。我在讲授这一节内容时重点介绍了二步序列法,收到了良好的教学效果。具体内容简介如下:
How to establish the reaction rate equation is an important part of the kinetics of the complex phase catalytic reaction. In the past, when teaching this section, most of them only introduced the conventional balance method and quasi-steady state processing method. Some existing textbooks and professional books published in China rarely introduced “two-step sequence method”. The method is based on the first two methods to simplify the process of establishing equations, and can give all the constants to have a clear physical meaning. When I was teaching this section I focused on the two-step sequence method and received good teaching results. Specific content is as follows: