Synthesis and Structure of a Cp^＊Ir Half-sandwich Complex Containing Azido and Bis（diphenylthiophosp

• 作 者: WU Fang-Hui DUAN Tai-Ke LU Lu-
• 机 构: MaterialChemistryLaboratory,InstituteofMolecularEngineeringandAppliedChemistry
• 出 处: 结构化学
• 发表日期: 2010年1期
• 关键词: 酰胺基 体结构 配体 叠氮 铱 合成 复合 夹心 iridium pentamethylcyclopentadienyl azide synthesis
• 基金项目: This work was supported by the National Natural Science Foundation of China andthe Program for New Century Excellent Talents in University （20771003 and NCET-06-0556）

The title complex [CpIr{N(Ph2PS)2}(N3)](N(Ph2PS)2=bis(diphenylthiophosphoryl)amide,Cp=pentamethylcyclopentadienyl) has been prepared and characterized by X-ray diffraction analysis.It crystallizes in monoclinic,space group P21/n with a=11.6946(1),b=18.927