Synthesis and Structure of Paramagnetic β-OctamolybdateComplex,[Fe（2,2′-bipy）3]2[Mo8O26]·6H2O

• 作 者: 宋立军 曾卉一 董振超 郭国聪 黄锦顺
• 机 构: StateKeyLaboratoryofStructuralChemistry
• 出 处: 结构化学
• 发表日期: 2004年2期
• 关键词: β-辛钼酸盐 铁配合物 2 2′-联吡啶 [Fe(2 2′-bipy)3]2[Mo8O26]·6H2O 顺磁性质 合成 晶体结构 EPR β-octa
• 基金项目: This work was supported by the Introduction of Overseas Elitists Program (No.IB990168),, the Chinese Academy of Sciences

A novel octamolybdate complex, [Fe(2,2′-bipy)3]2[Mo8O26]·6H2O has been synthesized via the hydrothermal technique, and it crystallizes in monoclinic, space group P21/c with two molecules in a unit cell:α=1.21512(5), b=1.36840(5), c=2.18823(9)nm,β=90.