Oxidative polymerization of hydroquinone using deoxycholic acid supramolecular template

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：yujia599

【摘要】

：

Polyhydroquinone (PHQ ) 是有 quinone/hydroquinone 氧化还原作用的氧化还原作用活跃的聚合物在主要的链的活跃单位并且可以在生物传感器和 biofuel 房间作为一个调停人有

【作者】

：

ZHANG AiJuan HE Jian GUAN Ying

【机构】

：

KeyLaboratoryofFunctionalPolymerMaterials,DepartmentofChemistry

【出处】

：

中国科学：化学英文版

【发表日期】

：

2012年5期

【关键词】

：

超分子模板氧化聚合对苯二酚脱氧胆酸氧化还原活性超分子组装生物燃料电池 DCA polyhydroquinone deoxycholic acid

【基金项目】

：

support from the National Natural Science Foundation of China （20974049）,the Ministry of Science and Technology of China （2007DFA50760）,Tianjin Committee of Science and Technology （10JCYBJC02000）,the

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Polyhydroquinone (PHQ ) 是有 quinone/hydroquinone 氧化还原作用的氧化还原作用活跃的聚合物在主要的链的活跃单位并且可以在生物传感器和 biofuel 房间作为一个调停人有潜在的应用。由对苯二酚(HQ ) 的氧化聚合， PHQ 能容易被综合，但是反应在产品的结构上缺乏控制。Deoxycholic 酸(DCA ) 作为一个超分子的模板被介绍控制反应。反应率在缓冲区那在 deionized 水里并且两次是 14 次那。DCA 模板增加不仅反应率，而且获得的聚合物的分子

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Oxidative polymerization of hydroquinone using deoxycholic acid supramolecular template

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