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本文报导了用国产常压MOCVD系统生长GaInP材料.研究GaInP的生长特性,用光致发光、扫描电镜、X光双晶衍射对材料进行表征.发现Ⅴ/Ⅲ比对GaInP的光学特性有很大影响.在温度680℃,Ⅴ/Ⅲ比为90的条件下得到Ga(0.51)In(0.49)P外延层的光致发光谱的半高宽为26meV,这是目前报导的最好结果.Ga(0.51)In(0.49)P的本征载流子浓度为1.1×10(15)cm(-3),晶格失配为4×10(-4).
This article reports the growth of GaInP material using a home-grown MOCVD system. The growth characteristics of GaInP were studied. The materials were characterized by photoluminescence, scanning electron microscopy and X-ray double crystal diffraction. It was found that V / III ratio has a great influence on the optical properties of GaInP. The half-width of the photoluminescence spectrum of Ga (0.51) In (0.49) P epitaxial layer obtained at 680 ℃ and V / Ⅲ ratio of 90 was 26meV, which is the best reported result . The intrinsic carrier concentration of Ga (0.51) In (0.49) P is 1.1 × 10 (15) cm (-3) and the lattice mismatch is 4 × 10 (-4).