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合成了TADNm,研究了TADNm与Ni(Ⅱ)的显色反应。在pH6.60的缓冲溶液中,0.020%SLS存在下,Ni(Ⅱ)与TADNm形成1:1的红色络合物,λmax为510nm,ε为5.0×104L·mol-1·cm-1,稳定常数为3.8×1012。方法用于合金中微量镍的测定,结果满意。
TADNm was synthesized and the color reaction of TADNm with Ni (Ⅱ) was studied. In the buffer solution of pH6.60, Ni (Ⅱ) forms a 1: 1 red complex with TADNm in the presence of 0.020% SLS, λmax is 510 nm and ε is 5.0 × 104 L · mol -1 cm -1, the stability constant is 3.8 × 1012. The method was applied to the determination of trace nickel in the alloy with satisfactory results.