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自从八十年代美国UCC首次合成出非硅铝酸盐的AlPO_4-n系列分子筛以米,由于其特殊的骨架结构和物化性质,引起人们的广泛重视.我们用乙二胺基乙醇作模板剂合成出AlPO_4-CJ_1.经多晶X射线衍射,红外光谱及扫描电镜等结构表征,证明其为纯的,新型无机微孔晶体,吸附实验证明其具有4(?)的孔道.AlPO_4-CJ_1的制备:反应物摩尔配比:1.0Al_2O_3:1.0F_2O_5:(1.0-1.8)乙二胺基乙醇:(90-120)H_2O.以铝源[硫酸铝水溶液(含Al_2O_37.04％)];磷源(磷酸铵);有机胺;水的次
Since the eighties UCC first synthesized non-aluminosilicate AlPO 4-n series zeolite in meters, due to its special framework structure and physico-chemical properties, attracted widespread attention.We use ethylenediamine-ethanol as a template synthesis The AlPO 4-CJ 1 was characterized by means of polycrystalline X-ray diffraction, infrared spectrum and scanning electron microscopy. It was proved that AlPO 4-CJ 1 was a pure new type of inorganic microporous crystal. : Molar ratio of reactants: 1.0Al_2O_3: 1.0F_2O_5: (1.0-1.8) Ethylenediaminoethanol: (90-120) H_2O. The aluminum source (aluminum sulfate aqueous solution containing Al_2O_37.04% Ammonium phosphate); organic amines; water times