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在金电极上,用电化学方法将单缺位Dawson型磷钨杂多酸盐a2-K10P2W17O6115H2O的阴离子(P2W17)掺杂到聚吡咯(PPy)薄膜中,制成PPy/P2W17/Au的H2O2传感器。研究了它对 H2O2电还原过程的催化机理.其 ipe与 CH2O2在 6.0× 10-5~8. 8×10-4 mol/L和8.8×10-4~6.0×10-3mol/L范围内呈良好的线性关系,检测下限为4.0×10-5mol/L。用于模拟水样中H2O2的测定,结果较满意.
On the gold electrode, the anions (P2W17) of mono-vacancies Dawson-type heteropolyphosphoric salt a2-K10P2W17O6115H2O were doped into polypyrrole (PPy) thin films electrochemically to produce PPy / P2W17 / Au H2O2 sensors . The catalytic mechanism of H2O2 reduction was studied. The ipe and CH2O2 at 6.0 × 10-5 ~ 8. The linear range was 8 × 10-4 mol / L and 8.8 × 10-4 ~ 6.0 × 10-3 mol / L with the detection limit of 4.0 × 10-5 mol / L. Used to simulate the determination of H2O2 in water samples, the results are satisfactory.