Assembly and Electrochemical Study of Transition Metal Substituted Polyoxometalates SiW11 NiO39^6- a

• 作 者: LüGui-qin DUJin-yan HUCha
• 机 构: InstituteforChemicalPhysics,InstituteforChemicalPhysics
• 出 处: 高等学校化学研究：英文版
• 发表日期: 2005年4期
• 关键词: 层状自组装 电化学行为 电催化还原 金属氧化物聚合物 4-氨基苯硫酚修饰玻碳电极 Polyoxometalate Layer-by-layer assembl
• 基金项目: SupportedbytheNationalNaturalScienceFoundationofChina(Nos.20331010and20271007)andSpecializedResearchFundfortheDoctoralProgramofHigherEducation(No.20030007014).

Via layer-by-layer assembly, the polyoxometalates of Keggin type, SiW11 O39 Ni(H2O)^6- (SiNiW11) and SiW11 O39Mn( H2O)^6-( SiMnW11 ) were first immobilized on a 4-aminothiophenol (4-ATP) modified glassy carbon electrode surface. The electrochemical behavi